Infrared study of OH−defects in KTiOPO4crystals
作者:
P. A. Morris,
M. K. Crawford,
B. Jones,
期刊:
Journal of Applied Physics
(AIP Available online 1992)
卷期:
Volume 72,
issue 11
页码: 5371-5380
ISSN:0021-8979
年代: 1992
DOI:10.1063/1.351976
出版商: AIP
数据来源: AIP
摘要:
Variations in the concentrations and distributions of the OH−defects present in flux and hydrothermal KTiOPO4(KTP) crystals, measured by infrared spectroscopy of single crystals, are attributed to differences in the growth environments and other nonhydrogenic defects present in the crystals. The concentrations of OH−have been estimated from the infrared data to be approximately 400 ppma (parts per million atomic) (3.0×1019cm−3) in the flux crystals, 1100–1500 ppma (0.74–1.1×1020cm−3) in the high‐temperature hydrothermal and 600 ppma (4.3×1019cm−3) in the low‐temperature hydrothermal crystals. A 3566 cm−1peak and a 3575 cm−1band are observed in all crystals. The integrated intensity of the OH−absorption band at 3566 cm−1increases at the expense of the 3575 cm−1band at higher temperatures in the high‐temperature hydrothermal crystals. Several OH−peaks (3490, 3455, 3428, 3420, and 3333 cm−1), which have strongly temperature‐dependent linewidths, are present in the hydrothermally grown KTP crystals. The temperature dependencies of their peak frequencies and widths are consistent with the presence of mobile protons in the lattice. The protons located in the 3490 and 3428 cm−1sites are believed to contribute to the ionic conductivity of the high‐conductivity high‐temperature hydrothermal crystals.
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