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Evaluation of free‐volume theories for solvent self‐diffusion in polymer–solvent systems

 

作者: J. S. Vrentas,   C. M. Vrentas,  

 

期刊: Journal of Polymer Science Part B: Polymer Physics  （WILEY Available online 1993）
卷期: Volume 31, issue 1  

页码: 69-76

 

ISSN:0887-6266

 

年代: 1993

 

DOI:10.1002/polb.1993.090310109

 

出版商: John Wiley&Sons, Inc.

 

关键词: free‐volume theories for solvent self‐diffusion in polymer‐solvent systems;penetrant self‐diffusion in polymer solutions and glassy polymers, free‐volume theories for;glassy polymers, theories for penetrant self‐diffusion coefficients in

 

数据来源: WILEY

 

摘要:

AbstractAn evaluation of free‐volume theories for solvent self‐diffusion is carried out using recent comprehensive data sets for penetrant self‐diffusion in polymer solutions. Different theories are compared, and free‐volume theories in the prediction of penetrant self‐diffusion coefficients in glassy polymer systems is also evaluated. © 1993 John Wiley

 

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