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The Cox–Merz rule extended: A rheological model for concentrated suspensions and other materials with a yield stress

 

作者: D. Doraiswamy,   A. N. Mujumdar,   I. Tsao,   A. N. Beris,   S. C. Danforth,   A. B. Metzner,  

 

期刊: Journal of Rheology  (AIP Available online 1991)
卷期: Volume 35, issue 4  

页码: 647-685

 

ISSN:0148-6055

 

年代: 1991

 

DOI:10.1122/1.550184

 

出版商: The Society of Rheology

 

关键词: Yield stress;Ceramic suspensions;Constitutive equation;Nonlinear viscoelasticity;Oscillatory behavior;Concentrated suspensions;STRESSES;SUSPENSIONS;YIELD STRENGTH;RHEOLOGY;CERAMICS;VISCOSITY;LIQUID FLOW;NONLINEAR PROBLEMS;SILICON;POLYETHYLENES

 

数据来源: AIP

 

摘要:

A nonlinear rheological model combining elastic, viscous, and yielding phenomena is developed in order to describe the rheological behavior of materials which exhibit a yield stress. A key feature of the formulation is the incorporation of a recoverable strain; it has a maximum value equal to the critical strain at which the transition from an elastic solid‐like response to a viscous shear thinning response occurs. An analysis is presented to enable determination of all the model parameters solely from dynamic measurements which are easily accessible experimentally. A rigorous correlation, analogous in form to the Cox–Merz rule, is shown to exist between the steady shear viscosity and the complex dynamic viscosity in terms of a newly defined ‘‘effective shear rate.’’ Experimental data obtained for a 70 vol % suspension of silicon particles in polyethylene indicate agreement with theoretical predictions for both the dynamic and steady shear behavior.

 

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