Dynamics of the Double Layer at the Polorizable Mercury-Electrolyte Interface
作者:
S.S. Bamji,
S.P. Bowen,
R.F. Tipsword,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1978)
卷期:
Volume 8,
issue 3
页码: 189-208
ISSN:0031-9104
年代: 1978
DOI:10.1080/00319107808084752
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The electric potential differences which arise across the length of capillary tubes containing IN Perchloric acid and mercury drops are studied experimentally and theoretically for conditions of constant acceleration and constant velocity of the mercury drops relative to the capillary walls. A relatively simple theory explains many features of the dependence of the potential difference on experimental parameters. The results suggest that by coupling mechanical measurements with electrochemical measurements could yield inferfacial parameters which are difficult to determine by electro chemistry alone.
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