Single‐Crystal Structure of the Solvent‐Separated Radical Ion Pair [9,10‐diphenylanthracene.⊖][Na⊕(THF)6] and its implication for cation solvation
作者:
Hans Bock,
Andreas John,
Christian Näther,
Zdenek Havlas,
Eva Mihokova,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1994)
卷期:
Volume 77,
issue 1
页码: 41-50
ISSN:0018-019X
年代: 1994
DOI:10.1002/hlca.19940770107
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
AbstractThe one‐electron transfer to large π‐delocalized hydrocarbons provides an interesting possibility to crystallize solvent‐separated ion‐pair salts containing optimally solvated cations. Accordingly, the reduction of 9,10‐diphenylanthracene in aprotic THF solution at a sodium metal mirror allows to grow dark‐blue prismatic crystals of its radical anion and sixfold THF‐solvated sodium cation. The structure of the radical anion is very similar to that recently published for the neutral molecule. According to AM1 hypersurface calculations based on the structural data, the phenyl twist angles obviously must be determined by lattice packing, and the negative charge is delocalized predominantly within the anthracene π system. The counter cation [Na⊕(THF)6], reported ordered for the first time, shows nearly octahedral coordination within a rather densily packed solvent shell. Due to the strong repulsions between the solvent molecules, its isodesmically calculated solvation enthalpy is smaller than that of the analogous dimethoxyethane co
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