The heterogeneous catalytic reaction between carbon monoxide and nitrous oxide over manganous oxide and cobalto-cobaltic oxide
作者:
Bordan Walter Krupay,
Robert Anderson Ross,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1978)
卷期:
Volume 56,
issue 1
页码: 10-16
ISSN:0008-4042
年代: 1978
DOI:10.1139/v78-002
出版商: NRC Research Press
数据来源: NRC
摘要:
The catalytic reaction between carbon monoxide and nitrous oxide has been studied on MnO from 493 to 573 K and on Co3O4from 383 to 493 K. The apparent activation energy on MnO was 130 ± 4 kJ mol−1, while for Co3O4, a change from 31 ± 4 to 105 ± 4 kJ mol−1was observed at 450 K. The rate-controlling step for the catalytic reaction on MnO was associated with the surface reaction between carbon monoxide and nitrous oxide in a manner similar to that previously reported for NiO, while for Co3O4, the rate-determining step was related to the formation of an intermediate surface carbonate. The changes inEAmay be a consequence of the surface reaction proceeding via a concerted redox reaction in the low temperature region and then to a stepwise mechanism at higher temperatures resulting from the presence of structurally and energetically different forms of the intermediate surface carbonate.
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