Stripping Potentiometry of Lead, Cadmium and Copper at a Nafion Coated Glassy Carbon Electrode with Encapsulated Mercury Acetate
作者:
Carlo Maccà,
Mark Bradshaw,
Arben Merkoci,
Geoffrey Scollary,
期刊:
Analytical Letters
(Taylor Available online 1997)
卷期:
Volume 30,
issue 6
页码: 1223-1234
ISSN:0003-2719
年代: 1997
DOI:10.1080/00032719708004051
出版商: Taylor & Francis Group
关键词: Stripping potentiometry;Potentiometric stripping analysis;Nafion;Lead;Cadmium;Copper
数据来源: Taylor
摘要:
The stripping potentiometric determination of lead, cadmium and copper with mercury film glassy-carbon electrodes coated with a Nafion membrane was investigated. The mercury film was plated using either mercury(II) acetate encapsulated within the Nafion membrane or a mercury(II) solution. Dissolved dioxygen was used as the stripping agent. The electrodes showed promising properties, particularly robustness and response repeatability. A linear dependence of the stripping time on concentration was found in the μg l−1concentration range (s.d. of intercept ≤ 0.3 μg l−1, r.s.d. of slope ≤ 1%, for both lead and cadmium).
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