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Studies on the texture of nematic solutions of a rod-like polymer 1. Distortion of the director field in a magnetic field

 

作者: BEIBEI DIAO,   GUYC. BERRY,  

 

期刊: Liquid Crystals  (Taylor Available online 1997)
卷期: Volume 22, issue 3  

页码: 225-238

 

ISSN:0267-8292

 

年代: 1997

 

DOI:10.1080/026782997209270

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The growth of the distortion of the director in an external field, and its relaxation on removal of the field are studied for nematic solutions of the rod-like poly(1,4-phenylene-2,6-benzobisthiazole), PBZT, over a range of concentration, polymer molecular weight and temperature. The twist viscosity and the order parameter are more weakly dependent on concentration than predicted for charged rod-like chains. This behaviour implies a short-range translational order in a direction orthogonal to the chain axis, induced by electrostatic interactions among the polycations on protonated PBZT. The relaxation gives a normal temperature dependence for the splay curvature elasticity, but that for the twist curvature is unexpectedly strong. This behaviour is interpreted as a weakening of the surface anchoring with increased temperature.

 

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