Studies on the texture of nematic solutions of a rod-like polymer 1. Distortion of the director field in a magnetic field
作者:
BEIBEI DIAO,
GUYC. BERRY,
期刊:
Liquid Crystals
(Taylor Available online 1997)
卷期:
Volume 22,
issue 3
页码: 225-238
ISSN:0267-8292
年代: 1997
DOI:10.1080/026782997209270
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The growth of the distortion of the director in an external field, and its relaxation on removal of the field are studied for nematic solutions of the rod-like poly(1,4-phenylene-2,6-benzobisthiazole), PBZT, over a range of concentration, polymer molecular weight and temperature. The twist viscosity and the order parameter are more weakly dependent on concentration than predicted for charged rod-like chains. This behaviour implies a short-range translational order in a direction orthogonal to the chain axis, induced by electrostatic interactions among the polycations on protonated PBZT. The relaxation gives a normal temperature dependence for the splay curvature elasticity, but that for the twist curvature is unexpectedly strong. This behaviour is interpreted as a weakening of the surface anchoring with increased temperature.
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