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Conformations of polydisperse polymer solutions: Bimodal distribution

 

作者: J. F. Joanny,   P. Grant,   P. Pincus,   L. A. Turkevich,  

 

期刊: Journal of Applied Physics  (AIP Available online 1981)
卷期: Volume 52, issue 10  

页码: 5943-5948

 

ISSN:0021-8979

 

年代: 1981

 

DOI:10.1063/1.328524

 

出版商: AIP

 

数据来源: AIP

 

摘要:

We use scaling arguments to construct the ’’phase diagram’’ of an athermal bimodal solution; i.e., a ternary system composed of long chains, short chains, and solvent. Qualitatively, the presence of short chains reduces the effective solvent quality as experienced by the long chains. We obtain asymptotic forms for the radii of gyration of both chains throughout the phase diagram.

 

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