Resonance Raman spectra of Cu‐porphin‐d4(meso) and Ni‐porphin, and the infrared spectrum of Cu‐porphin‐d4
作者:
A. L. Verma,
M. Asselin,
S. Sunder,
H. J. Bernstein,
期刊:
Journal of Raman Spectroscopy
(WILEY Available online 1976)
卷期:
Volume 4,
issue 3
页码: 295-303
ISSN:0377-0486
年代: 1976
DOI:10.1002/jrs.1250040311
出版商: John Wiley&Sons, Ltd.
数据来源: WILEY
摘要:
AbstractThe resonance Raman spectra are presented for Ni‐porphin and Cu‐porphin‐d4(meso) as dilute solutions in CS2and C2Cl4using an Ar+laser and a tunable Rhodamine 6G dye laser. The Raman features are assigned to the different vibrational species on the basis of their depolarization data. The assignment of 14 features in the spectrum of Cu‐porphin‐d4and 13 features in the spectrum of Cu‐porphin and Ni‐porphin is discussed by comparing the spectra of the three molecules. Also the infrared spectrum of Cu‐porphin‐d4as a solid dispersed in CsI matrix is reported for the 20
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