The Synthesis and Properties of Poly(Aromatic Ketones)
作者:
M.J. Mullins,
E.P. Woo,
期刊:
Journal of Macromolecular Science, Part C
(Taylor Available online 1987)
卷期:
Volume 27,
issue 2
页码: 313-341
ISSN:1532-1797
年代: 1987
DOI:10.1080/07366578708081918
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
More than two decades ago, Bonner reported the first preparation of poly (aromatic ketones) (PAK) by aluminum chloride-catalyzed acylation of diphenyl ether with aromatic diacid chlorides [1]. These were low molecular weight materials because of solubility limitations. In the intervening years, significant progress has been made in synthetic methodology, and now a large variety of structures is available for study. Unlike poly-Caryl sulfones) which are typically amorphous, most PAK's exhibit partial crystallinity, usually with melting points above 300°C. Like the sulfones, the ketone polymers possess high thermal stability and exhibit excellent electrical and mechanical properties. The development of this interesting polymer family is the subject of this review.
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