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PATTERN FORMATION IN SOLID FILM GROWTH DURING CVD

 

作者: JACOBJ. THIART,   DARIUSZ ORLICKI,   VLADIMIR HLAVACEK,  

 

期刊: Chemical Engineering Communications  (Taylor Available online 1996)
卷期: Volume 152-153, issue 1  

页码: 189-209

 

ISSN:0098-6445

 

年代: 1996

 

DOI:10.1080/00986449608936562

 

出版商: Taylor & Francis Group

 

关键词: Pattern formation;CVD;Interface dynamics;Stability analysis;Morphology

 

数据来源: Taylor

 

摘要:

This paper deals with the evolution of a gas-solid interface during growth of amorphous CVD films. The aim of the analysis is to show that a comprehensive gas-solid CVD model may simplify significantly under conditions of two limiting cases: kinetic and diffusion-limited growth. The linear stability behavior of the simplified model was found to be almost identical to that of the original and more comprehensive model. It was found that planar film growth was inherently stable under kinetically controlled deposition conditions, but under diffusion-limited conditions, planar film stability depended on the magnitude of the dimensionless group 9Pe, which represents a Damkdhler number of deposition. Numerical solution of the simplified model showed that an increase in 9pe adversely affected the uniformity of film deposition. Predicted morphological phenomena were found to be very similar to experimental observations (Viljoen,et al,1994).

 

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