A MOLECULAR MODEL FOR A PHOSPHOLIPID‐RETINALDEHYDE COMPLEX ABSORBING AT 500 nm
作者:
NORMAN E. SHARPLESS,
RALPH G. ADAMS,
WILLIAM H. JENNINGS,
期刊:
Photochemistry and Photobiology
(WILEY Available online 1971)
卷期:
Volume 13,
issue 1
页码: 21-26
ISSN:0031-8655
年代: 1971
DOI:10.1111/j.1751-1097.1971.tb06087.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
Abstract—–The structure of a complex formed from retinaldehyde and ethanolamine phosphoglyceride has been proposed as a Schiff's base stabilized byπ–πinteraction between the double bond of an oleic acid group (Δ9) and the 9–10 double bond of the retinaldehyde chain. Considerations of stereochemistry and simple MO theory indicate the proposed structure to be energetically favored, and its absorption maximum is predicted by free elect
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