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A MOLECULAR MODEL FOR A PHOSPHOLIPID‐RETINALDEHYDE COMPLEX ABSORBING AT 500 nm

 

作者: NORMAN E. SHARPLESS,   RALPH G. ADAMS,   WILLIAM H. JENNINGS,  

 

期刊: Photochemistry and Photobiology  (WILEY Available online 1971)
卷期: Volume 13, issue 1  

页码: 21-26

 

ISSN:0031-8655

 

年代: 1971

 

DOI:10.1111/j.1751-1097.1971.tb06087.x

 

出版商: Blackwell Publishing Ltd

 

数据来源: WILEY

 

摘要:

Abstract—–The structure of a complex formed from retinaldehyde and ethanolamine phosphoglyceride has been proposed as a Schiff's base stabilized byπ–πinteraction between the double bond of an oleic acid group (Δ9) and the 9–10 double bond of the retinaldehyde chain. Considerations of stereochemistry and simple MO theory indicate the proposed structure to be energetically favored, and its absorption maximum is predicted by free elect

 

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