Plagioclase compositions vary from An0.1–2.5to An32with increasing grade in chlorite zone to oligoclase zone quartzofeldspathic schists, Franz Josef‐Fox Glacier area, Southern Alps, New Zealand. This change is interrupted by the peristerite composition gap in rocks transitional between greenschist and amphibolite facies grade. Oligoclase (An20‐24) and albite (An0.1–0.5) are found in biotite zone schists below the garnet isograd. With increasing grade, the plagioclase compositions outline the peristerite gap, which is asymmetric and narrows to compositions of An12and An6near the top of the garnet zone. In any one sample, oligoclase is the stable mineral in mica‐rich layers above the garnet isograd, whereas albite and oligoclase exist in apparent textural equilibrium in adjacent quartz‐plagioclase layers. The initial appearance of oligoclase in both layers results from the breakdown of epidote and possibly sphene. Carbonate is restricted to the quartz‐plagioclase rich layers and probably accounts for the more sodic composition of oligoclase in these layers. The formation of more Ca‐rich albite and more Na‐rich oligoclase near the upper limit of the garnet zone coincides with the disappearance of carbonate and closure of the peristerite gap. Garnet appears to have only a localized effect on Ca‐enrichment of plagioclase in mica‐rich layers within the garnet zone. The Na‐content of white mica increases sympathetically with increasing Ca‐content of oligoclase and metamorphic grade.Comparison of the peristerite gap in the Franz Josef‐Fox Glacier schists and schists of the same bulk composition in the Haast River area, 80 km to the S, indicates that oligoclase appears and epidote disappears at lower temperatures, and that the composition gap between coexisting albite and oligoclase is narrower in the Franz Josef‐Fox Glacier area. It is suggested that a higher thermal gradient (38‐40°C/km) and variations in Si/Al ordering during growth of the plagioclases between the two areas may account for these differences. In the Alpine schists the peristerite gap exists over a temperature and pressure interval of about 370‐515°