Chemical shifts of thallium resonance spectra in solutions of thallous salts
作者:
R. Freeman,
R.P.H. Gasser,
R.E. Richards,
D.H. Wheeler,
期刊:
Molecular Physics
(Taylor Available online 1959)
卷期:
Volume 2,
issue 1
页码: 75-84
ISSN:0026-8976
年代: 1959
DOI:10.1080/00268975900100071
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Chemical shifts of the thallium nuclear resonance have been measured in solutions of thallous hydroxide, fluoride, acetate, formate, nitrate, and perchlorate of varying concentrations and in the presence of added substances. At low concentrations the chemical shift varies non-linearly with concentration of anion and can be correlated with the formation of ion-pairs. In stronger solutions the variation of chemical shift becomes linear, and is attributed to interactions between the ion-pairs and the added substances.
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