The Potentiodynamic Electrooxidation of Glycerol on Platinized Platinum Electrodes
作者:
R.S. Gonçalves,
W.E. Triaca,
T. Rabockai,
期刊:
Analytical Letters
(Taylor Available online 1985)
卷期:
Volume 18,
issue 8
页码: 957-973
ISSN:0003-2719
年代: 1985
DOI:10.1080/00032718508066191
出版商: Taylor & Francis Group
关键词: glycerol;electrooxidation;Pt electrode
数据来源: Taylor
摘要:
The electrooxidation of adsorbed glycerol species on platinized platinum electrodes in 1 N H2SO4was studied by cyclic voltammetry and the potential step method. The main conclusions are: the electrooxidation of glycerol at potentials lower than 1.2 V (vs, RHE) is a complex reaction in which more than one adsorbed intermediates are probably involved. The adsorbed intermediates exhibit ageing effects, at higher potentials a chemical interaction between glycerol and adsorbed oxygen occurs and the overall process is controlled by mass transfer.
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