Active Sites Structure and Mechanism of Stereospecific Polymerization of α-Olefins and Dienes Employing Ziegler-Natta Catalysts
作者:
K.S. Minsker,
M.M. Karpasas,
G.E. Zaikov,
期刊:
Journal of Macromolecular Science, Part C
(Taylor Available online 1987)
卷期:
Volume 27,
issue 1
页码: 1-90
ISSN:1532-1797
年代: 1987
DOI:10.1080/07366578708078640
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Stereospecific polymerization of α-olefin and diene hydrocarbons in the presence of catalysts of a new type proposed by Ziegler and Natta is a significant discovery of the twentieth century in the chemistry of macromolecular compounds. Heterogeneous Ziegler-Natta catalysts involving Ti and V trichlorides in combination with organoaluminum compounds have been widely used for nearly 30 years in commercial stereospecific polymerization of a number of o-olefins (propylene, hexene-l,4-methyl-pentene-1, etc.) and dienes (butadiene, isoprene, etc.). However, despite the great success achieved in practical implementation of the processes there isnocommon point of viewsofar and broad discussions are still under way as to the mechanism of polymerization and stereoregulation in the presence of the above catalysts.
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