Characterization of chemisorbed species in CO/H2and CO2/H2reactions. Evolutive behaviour of the species
作者:
J. P. Hindermann,
A. Deluzarche,
R. Kieffer,
A. Kiennemann,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1983)
卷期:
Volume 61,
issue 1
页码: 20-28
ISSN:0008-4034
年代: 1983
DOI:10.1002/cjce.5450610103
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractBy applying the chemical trapping method to the hydrocondensation reaction of carbon monoxide, we propose a reaction scheme with some novel interesting features. In the chemisorption of CO on Ni/SiO2, Ni/Al2O3, Co, Co/Al2O3we detected species bonded both through the C and O ends of the molecule. This chemisorbed CO can be the intermediate of the dissociation of CO or lead to the formation of a formyl species by reaction with hydrogen. The competition of these two reactions can lead to hydrocarbons or to alcohols.
点击下载:
PDF
(795KB)
返 回