Reactions of Sulfur Containing Phenolic Antioxidants for Elastomers
作者:
Hansrudolf Meier,
Hanspeter Kuenzi,
Gerrit Knobloch,
Guenther Rist,
Martin Szelagiewicz,
期刊:
Phosphorus, Sulfur, and Silicon and the Related Elements
(Taylor Available online 1999)
卷期:
Volume 153,
issue 1
页码: 275-300
ISSN:1042-6507
年代: 1999
DOI:10.1080/10426509908546440
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Alkyl-hydroxybenzylthioethers are efficient storage and processing stabilizers for elastomers and adhesives. Especially alkyl-(2-hydroxybenzyl)thioethers represent an intramolecular combination of a primary and secondary antioxidant, i.e. a phenolic and a thioether moiety in an optimized spatial arrangement. The mechanism of their intramolecular synergism was investigated. The best overall stabilizers are 2,4-bis(alkylthiomethyl)-6-methylphenols, e.g. AOl, in contrast to 2,6-dialkyl-4-alkylthiomethylphenols(B), 4-alkyl-2,6-bis(alkylthiomethyl)phenols C.
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