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Reactions of Sulfur Containing Phenolic Antioxidants for Elastomers

 

作者: Hansrudolf Meier,   Hanspeter Kuenzi,   Gerrit Knobloch,   Guenther Rist,   Martin Szelagiewicz,  

 

期刊: Phosphorus, Sulfur, and Silicon and the Related Elements  (Taylor Available online 1999)
卷期: Volume 153, issue 1  

页码: 275-300

 

ISSN:1042-6507

 

年代: 1999

 

DOI:10.1080/10426509908546440

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Alkyl-hydroxybenzylthioethers are efficient storage and processing stabilizers for elastomers and adhesives. Especially alkyl-(2-hydroxybenzyl)thioethers represent an intramolecular combination of a primary and secondary antioxidant, i.e. a phenolic and a thioether moiety in an optimized spatial arrangement. The mechanism of their intramolecular synergism was investigated. The best overall stabilizers are 2,4-bis(alkylthiomethyl)-6-methylphenols, e.g. AOl, in contrast to 2,6-dialkyl-4-alkylthiomethylphenols(B), 4-alkyl-2,6-bis(alkylthiomethyl)phenols C.

 

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