Molecular Recognition by Hydrogen Bonding in Polyelectrolyte Multilayers
作者:
André Laschewsky,
Erik Wischerhoff,
Steffen Denzinger,
Helmut Ringsdorf,
Arnaud Delcorte,
Patrick Bertrand,
期刊:
Chemistry – A European Journal
(WILEY Available online 1997)
卷期:
Volume 3,
issue 1
页码: 34-38
ISSN:0947-6539
年代: 1997
DOI:10.1002/chem.19970030107
出版商: WILEY‐VCH Verlag
关键词: hydrogen bonds;molecular recognition;polyelectrolyte multilayers;surface chemistry;thin films
数据来源: WILEY
摘要:
AbstractFunctional polyanions were prepared by copolymerization of sulfopropyl acrylate and sulfopropyl methacrylate with monomers bearing triaminopyrimidine or barbituric acid functionalities, respectively. Functionalized polyelectrolyte multilayers were assembled from these copolymers by stepwise alternating adsorption with poly(choline methacrylate). These multilayers are suited for molecular recognition of substrates that are complementary to the functional groups incorporated. Thus, multilayers containing triaminopyrimidine moieties selectively bind barbituric acid, and vice versa, when exposed to solutions of the 1:1 complex of barbituric acid and triaminopyrimidine. The molecular recognition process was monitored by UV/Vis spectroscopy, time‐of‐flight secondary ion mass spectroscopy (ToF‐SIMS), and photoelectron spectroscopy (XPS). Remarkably, after successful recognition and binding of the complementary substrates to the multilayers, the stepwise layering could be cont
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