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On Mayer's ionic solution theory

 

作者: HaroldL. Friedman,  

 

期刊: Molecular Physics  (Taylor Available online 1959)
卷期: Volume 2, issue 1  

页码: 23-38

 

ISSN:0026-8976

 

年代: 1959

 

DOI:10.1080/00268975900100031

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

This theory, which is based upon McMillan and Mayer's cluster expansion of the grand partition function, is extended to include all of the components of the potentials of average force between sets of solute molecules or ions in the solvent at infinite dilution. The resulting cluster integral sum, which is a sum of integrals over an infinite number of infinite series of Mayer prototype graphs, is transformed into the sum of a single infinite series of integrals on graphs involving new types of bonds. These bonds are defined in a way first suggested by Meeron. There results a compact expression for the cluster integral sum.

 

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