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Low temperature Raman spectrum of xenon diatoms

 

作者: Y. Le Duff,   R. Ouillon,   V. Chandrasekharan,   B. Silvi,  

 

期刊: Molecular Physics  (Taylor Available online 1987)
卷期: Volume 62, issue 5  

页码: 1065-1077

 

ISSN:0026-8976

 

年代: 1987

 

DOI:10.1080/00268978700102781

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The depolarized Raman spectrum of xenon at low temperature of 193K is reported. The contributions of the bound dimers in the pure rotation and vibration rotation region are enhanced at this low temperature. The experimental profile is compared with the quantum mechanical calculation using different models of the interaction polarizability anisotropy. The BWLSL X2 potential and DID with hyperpolarizability correction gives extremely good agreement with experiment.

 

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