Synthesis of polybenzimidazoles with sulfonic acid groups
作者:
Keikichi Uno,
Kazuma Niume,
Yasuhisa Iwata,
Fujio Toda,
Yoshio Iwakura,
期刊:
Journal of Polymer Science: Polymer Chemistry Edition
(WILEY Available online 1977)
卷期:
Volume 15,
issue 6
页码: 1309-1318
ISSN:0360-6376
年代: 1977
DOI:10.1002/pol.1977.170150602
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
Abstract2‐Sulfoterephthalic acid (STA) and disulfoisophthalic acid (DSIA) were synthesized through the sulfonation and the oxidation ofm‐ andp‐xylene. The polycondensation reactions of STA and DSIA with aromatic tetraamines gave polybenzimidazoles which contained one or two sulfonic acid groups for each repeating unit. The polymer obtained was soluble in sulfuric acid, some organic solvents, and aqueous strong alkaline solution. The polymers were stable up to 400°C, but they gave polybenzimidazoles above 400°C by eliminating sulfonic acid groups, instead of ring
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