Voltammetric Stripping Analysis of Copper in Distilled Beverages using Solid Electrodes
作者:
P.J.S. Barbeira,
N.R. Stradiotto,
期刊:
Analytical Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 10
页码: 2071-2080
ISSN:0003-2719
年代: 1999
DOI:10.1080/00032719908542953
出版商: Taylor & Francis Group
关键词: copper;alcoholic beverages;stripping voltammetry;solid electrode
数据来源: Taylor
摘要:
This work describes the determination "in natura" of copper ions in alcoholic distilled beverages by anodic stripping voltammetry without previous treatment or addition of supporting electrolyte, using a glassy carbon electrode. The choice of an appropriate stripping voltammetric method minimizes the organic content influence and assures the good reproductivity of the measurements. The reliability of the method was tested comparing the results with the anodic stripping voltammetry, with a hanging mercury drop electrode, and atomic absorption spectrometry giving differences of about 7%. The method allows to determine copper ion in the μg L−1concentration range.
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