Measurement of Absolute Propagation and Termination Rate Constants for Alkylperoxyls in Solution by the Hydroperoxide Method
作者:
J. A. Howard,
期刊:
Israel Journal of Chemistry
(WILEY Available online 1984)
卷期:
Volume 24,
issue 1
页码: 33-37
ISSN:0021-2148
年代: 1984
DOI:10.1002/ijch.198400006
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractKinetic and product studies of liquid phase autoxidations in the presence of high concentrations of alkyl hydroperoxides have enabled absolute propagation and termination rate constants for alkylperoxyls to be measured. A large number of rateconstants and activation parameters have been accumulated over the past few years bythis technique and the highlights of this work are presented in this review.
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