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Polarography of Alkali Metal Complexes of Macrotetrolides: Alkyl Substituents and Complex Stability

 

作者: K. Angelis,  

 

期刊: Analytical Letters  （Taylor Available online 1975）
卷期: Volume 8, issue 12  

页码: 895-900

 

ISSN:0003-2719

 

年代: 1975

 

DOI:10.1080/00032717508059066

 

出版商: Taylor & Francis Group

 

关键词: marotetrolide complexes;substituent effect;stability constants

 

数据来源: Taylor

 

摘要:

The stability constants determined experimentally were correlated with Gibbs energies of ion—ligand interaction on the electrostatic level. Total charges on individual ligand atoms were calculated using the extended Hückel method (EHT). The inductive effect of the methyl group caused an increase of the stability constants for the macrotetrolides.

 

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