THERMOGRAVIMETRY OF THE DEHYDRATION OF Mg(OH)2
作者:
R. C. Turner,
I. Hoffman,
D. Chen,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1963)
卷期:
Volume 41,
issue 2
页码: 243-251
ISSN:0008-4042
年代: 1963
DOI:10.1139/v63-039
出版商: NRC Research Press
数据来源: NRC
摘要:
The DTG curves for the dehydration of a number of preparations of Mg(OH)2were determined. Equations necessary to calculate energies of activation and rate constants from these curves were derived on the basis of a two-thirds-order process for dehydration. It was found that the energy of activation was about 5 kcal greater for naturally occurring than for precipitated Mg(OH)2. This was interpreted to mean that there was a difference in the energy levels of the two preparations, and therefore a difference in their apparent solubility products. Differences obtained in the DTG curves for four different preparations of Mg(OH)2indicated the probability of a series of energy levels for Mg(OH)2.
点击下载:
PDF
(295KB)
返 回