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THERMOGRAVIMETRY OF THE DEHYDRATION OF Mg(OH)2

 

作者: R. C. Turner,   I. Hoffman,   D. Chen,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1963)
卷期: Volume 41, issue 2  

页码: 243-251

 

ISSN:0008-4042

 

年代: 1963

 

DOI:10.1139/v63-039

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The DTG curves for the dehydration of a number of preparations of Mg(OH)2were determined. Equations necessary to calculate energies of activation and rate constants from these curves were derived on the basis of a two-thirds-order process for dehydration. It was found that the energy of activation was about 5 kcal greater for naturally occurring than for precipitated Mg(OH)2. This was interpreted to mean that there was a difference in the energy levels of the two preparations, and therefore a difference in their apparent solubility products. Differences obtained in the DTG curves for four different preparations of Mg(OH)2indicated the probability of a series of energy levels for Mg(OH)2.

 

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