Thermodynamics of substituted coumarin VII: Potentiometric and spectrophotometric studies of 1-acetyl-2-(coumarin-iminecarboxamide-3-yl) hydrazine transition metal complexes
作者:
A.A. El-bindary,
期刊:
Spectroscopy Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 3
页码: 383-395
ISSN:0038-7010
年代: 1999
DOI:10.1080/00387019909349992
出版商: Taylor & Francis Group
关键词: 1-acetyl-2-(coumariniminecarboxamide-3-yl) hydrazine;dissociation and stability constants;thermodynamic functions
数据来源: Taylor
摘要:
The dissociation constant of l-acetyl-2-(coumariniminecarboxamide-3-yl) hydrazine (ACCH) has been determined potentiometrically in 0.1 M KC1 and 40% (v/v) ethanol-water mixture. The stepwise stability constants of the formed complexes of Mn2+, Co2+, Ni2+, Cu2+, Zn2+and UO22+with ACCH have been determined. The stability constants were found to UO22+> Cu2+> Zn2+> Ni2+< CO2+< Mn2+. The effect of temperature on the dissociation of ACCH and the stability of its formed complexes were studied. The corresponding thermodynamic functions were also determined and discussed. The spectral data of ACCH were investigated in pure organic solvents as well as in Britton Robinson buffer solutions of varying pH values. The dissociation constant pKH1of ACCH and the overall stability constants logβ of their complexes were determined in 20% (v/v) ethanol-water mixture at 298K.
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