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Chronopotentiometric Study of the Reduction of Trivalent Curium in Molten (Li-K)Cl Eutectic

 

作者: L. Martinot,   J. Reul,   G. Duyckaerts,   W. Müller,  

 

期刊: Analytical Letters  （Taylor Available online 1975）
卷期: Volume 8, issue 4  

页码: 233-239

 

ISSN:0003-2719

 

年代: 1975

 

DOI:10.1080/00032717508058204

 

出版商: Taylor & Francis Group

 

关键词: electrochemistry;chronopotentiometry;diffusion;molten salt;curium

 

数据来源: Taylor

 

摘要:

A chronopotentiometric study of the reduction Cm(III) + 3e → Cm(0) is reported. The diffusion coefficient increases from 3.6×10−6cm2sec−1to 17.2×10−6cm2sec−1in the temperature range 400−550°C. Diffusion data of various +1, +2, +3 and +4 ions are compared with regard to the charge density of the ions.

 

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