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Quantitative Laser-Saturated Fluorescence Measurements of Nitric Oxide in a Heptane Spray Flame

 

作者: CLAYTON S. COOPER,   NORMAND M LAURENDEAU,  

 

期刊: Combustion Science and Technology  (Taylor Available online 1997)
卷期: Volume 127, issue 1-6  

页码: 363-382

 

ISSN:0010-2202

 

年代: 1997

 

DOI:10.1080/00102209708935701

 

出版商: Taylor & Francis Group

 

关键词: Laser-Saturated Fluorescence (LSF);Laser-Saturated Fluorescence (LSF);spray flame

 

数据来源: Taylor

 

摘要:

We report spatially resolved laser-saturated fluorescence measurements of NO concentration in a pre-heated.lean-direct injection (LDI) spray flame at atmospheric pressure. The spray is produced by a hollow-cone, pressure-atomized nozzle supplied with liquid heptane. NO is excited via the Q2(26.5) transition of the γ(O, 0) band. Detection is performed in a 2-nm region centered on the γ(O, 1) band. Because of the relatively close spectral spacing between the excitation (226 nm) and detection wavelengths (236 nm), the γ(O, 1) band of NO cannot be isolated from the spectral wings of the Mie scattering signal produced by the spray. To account for the resulting superposition of the fluorescence and scattering signals, a background subtraction method has been developed that utilizes a nearby non-resonant wavelength. Excitation scans have been performed to locate the optimum off-line wavelength. Detection scans have been performed at problematic locations in the flame to determine possible fluorescence interferences from UHCs and PAHs at both the on-line and off-line excitation wavelengths. Quantitative radial NO profiles are presented and analyzed so as to better understand the operation of lean-direct injectors for gas turbine combustors.

 

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