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Enhanced cluster mobilities on Pt(111) during film growth from the vapor phase

 

作者: V. Chirita,   E. P. Mu¨nger,   J.-E. Sundgren,   J. E. Greene,  

 

期刊: Applied Physics Letters  (AIP Available online 1998)
卷期: Volume 72, issue 1  

页码: 127-129

 

ISSN:0003-6951

 

年代: 1998

 

DOI:10.1063/1.120664

 

出版商: AIP

 

数据来源: AIP

 

摘要:

We use molecular dynamics simulations to follow the dynamics of small two-dimensional Pt clusters on Pt(111) at 1000 K. While close-packedPt7heptamers are extremely stable structures, the addition of a single cluster vacancy or an on-top adatom immediately results in intracluster bond breaking, reconfigurations, rotations, the introduction of stacking faults, and greatly enhanced cluster diffusion rates. Mapping center-of-mass motion for total simulation times >145 ns revealed increases in cluster velocities by more than an order of magnitude with cluster migration occurring primarily by concerted motion and a novel diffusion mechanism involving double shearing of dimers/trimers. Contrary to some previous reports, edge-atom diffusion plays only a minor role. ©1998 American Institute of Physics.

 

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