A Method for the Preparation of Methylmetal Compounds
作者:
W. Sundermeyer,
W. Verbeek,
期刊:
Angewandte Chemie International Edition in English
(WILEY Available online 1966)
卷期:
Volume 5,
issue 1
页码: 1-6
ISSN:0570-0833
年代: 1966
DOI:10.1002/anie.196600011
出版商: Hüthig&Wepf Verlag
关键词: Methyl metal compounds
数据来源: WILEY
摘要:
AbstractA new method has been developed for the preparation of methylmetal compounds from methyl chloride and the chlorides of boron, aluminum, silicon, tin, phosphorus, antimony, or mercury. Fused salts are used as solvents, and metals are suspended in these to act as halogen acceptors. The metals are recovered, together with chlorine, by electrolysis. This process, which can be carried out continuously and quantitatively, can be used for the preparation of technically important methylmetal compounds that cannot be obtained directly by the “Mülheim aluminum alkyl metho
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