Ultrasonic Examination of Proton‐Transfer Reactions in Aqueous Solutions of Glycine
作者:
Matthew Hussey,
Peter D. Edmonds,
期刊:
The Journal of the Acoustical Society of America
(AIP Available online 1971)
卷期:
Volume 49,
issue 4B
页码: 1309-1316
ISSN:0001-4966
年代: 1971
DOI:10.1121/1.1912494
出版商: Acoustical Society of America
数据来源: AIP
摘要:
This paper reports a comprehensive experimental investigation, utilizing ultrasonic techniques to study the kinetics of proton‐transfer reactions in nondilute aqueous solutions of amino acids. Ultrasonic absorption and velocity measurements in the range of frequencies 10–130 MHz and ofpH 0.96–11.6 are analyzed in terms of single relaxation behavior. Activity coefficients are calculated by three methods; the method based upon standard ionic radii and the mean dielectric constant of the solutions is found to yield the most acceptable estimates. The dependencies of rate constants upon initial concentration of solute, ionic strength, and temperature are displayed in the range 0.25M–1.0M, 0.25M–1.0M, and 22°–37°C, respectively. It is concluded that proton‐transfer reactions at amino and carboxyl groups cannot be responsible for significant contributions to the total ultrasonic absorption coefficient of blood in the physiological range ofpH.
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