首页   按字顺浏览 期刊浏览 卷期浏览 Structure Formation Phenomena During Phase Inversion. II. Semiflexible Polymers and Liq...
Structure Formation Phenomena During Phase Inversion. II. Semiflexible Polymers and Liquid Crystallinity

 

作者: KONSTANTINOSG. BELTSIOS,   MARIACELESTE MORUA BEDARD,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 2000)
卷期: Volume 39, issue 5-6  

页码: 623-644

 

ISSN:0022-2348

 

年代: 2000

 

DOI:10.1081/MB-100102475

 

出版商: Taylor & Francis Group

 

关键词: Cellulose acetate;Glass transition;Liquid crystallinity;Lyotropic gelation;Membrane structure formation;Phase inversion;Semiflexible polymer

 

数据来源: Taylor

 

摘要:

The issue of isotropic-anisotropic equilibria contributions to structure formation of phase inversion (PI) membranes of semiflexible polymers such as cellulose derivatives is addressed. Two types of ternary phase diagrams pertinent to the PI of semiflexible polymer dopes are suggested, and modes of phase separation that control structure formation are described. Alternative interpretations for certain earlier structural observations in cellulose acetate (CA) membranes are proposed. Discussions of the lyotropic polymer gelation modes and the effect of glass formation on the progress of PI structural transformations are included.

 

点击下载:  PDF (361KB)



返 回