Structure Formation Phenomena During Phase Inversion. II. Semiflexible Polymers and Liquid Crystallinity
作者:
KONSTANTINOSG. BELTSIOS,
MARIACELESTE MORUA BEDARD,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 2000)
卷期:
Volume 39,
issue 5-6
页码: 623-644
ISSN:0022-2348
年代: 2000
DOI:10.1081/MB-100102475
出版商: Taylor & Francis Group
关键词: Cellulose acetate;Glass transition;Liquid crystallinity;Lyotropic gelation;Membrane structure formation;Phase inversion;Semiflexible polymer
数据来源: Taylor
摘要:
The issue of isotropic-anisotropic equilibria contributions to structure formation of phase inversion (PI) membranes of semiflexible polymers such as cellulose derivatives is addressed. Two types of ternary phase diagrams pertinent to the PI of semiflexible polymer dopes are suggested, and modes of phase separation that control structure formation are described. Alternative interpretations for certain earlier structural observations in cellulose acetate (CA) membranes are proposed. Discussions of the lyotropic polymer gelation modes and the effect of glass formation on the progress of PI structural transformations are included.
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