首页   按字顺浏览 期刊浏览 卷期浏览 Redox Behaviour of Phenolic Porphyrins in Basic Solutions: A Reappraisal
Redox Behaviour of Phenolic Porphyrins in Basic Solutions: A Reappraisal

 

作者: MilgromLionel R.,   YahiogluGokhan,   JogiyaNeha N.,  

 

期刊: Free Radical Research  （Taylor Available online 1996）
卷期: Volume 24, issue 1  

页码: 19-29

 

ISSN:1071-5762

 

年代: 1996

 

DOI:10.3109/10715769609087996

 

出版商: Taylor&Francis

 

数据来源: Taylor

 

摘要:

Phenolic porphyrins 1, 4, and 5 form stable phenoxyl radicals 3, 6, and 7 in deoxygenated as well as oxygenated basic solutions. Mechanistic schemes are presented, involving coupled disproportionation and conproportionation reactions, that do not require oxygen involvement in the redox processes leading to phenoxyl radicals.

 

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