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Coniothyriol, an Uncommon Polyketide fromConiothyrium sporulosum

 

作者: N.Buarque De Gusmño,   M. Kaouadji,   R. Steiman,   F. Seigle-murandi,   J. Ulrichc,  

 

期刊: Natural Product Letters  （Taylor Available online 1993）
卷期: Volume 2, issue 4  

页码: 287-292

 

ISSN:1057-5634

 

年代: 1993

 

DOI:10.1080/10575639308043824

 

出版商: Taylor & Francis Group

 

关键词: Coniothyrium sporuiosum;Coelomycetes;Sphaeropsidales;coniothyriol;4,7-dioxa-3,10-dioxo-11-hydroxy-2-rnethyl-6-rnethylene-tricyclo [6.3.3.0.01,5]undecane;NMR

 

数据来源: Taylor

 

摘要:

Coniothyriol, a new fungal metabolite has been isolated from the ethyl acetate extractable fraction ofConiothyrium sporulosumbroth. Its structure was identified as rel-(2R,5R,8R,11S)-4,7-dioxa-3,10-dioxo-11-hydroxy-2-methyl-6-methylene-tricyclo[6.3.3.0.01,5]undecane on the basis of spectroscopic data relative to both the natural product and the monoacetyl derivative.

 

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