Some temperature dependent effects on the optical absorption line shape of paramagnetic ions
作者:
R. Englman,
期刊:
Molecular Physics
(Taylor Available online 1960)
卷期:
Volume 3,
issue 1
页码: 23-34
ISSN:0026-8976
年代: 1960
DOI:10.1080/00268976000100031
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The temperature variations of the total intensity and of the mean energy of optical absorption in hydrated paramagnetic salts are calculated on the assumption that the absorbing ion and its coordinated ligands form an isolated complex. These calculations take into account the anharmonicities in the vibrational motion of the ligands. Comparison with experimental data indicates a rather large amount of anharmonicity.
点击下载:
PDF (483KB)
返 回