Quasiliving Carbocationic Poiymerization. III. Quasiliving Polymerization of lsobutylene
作者:
J. Puskás,
G. Kaszás,
J.P. Kennedy,
T. Kelen,
F. Tüdös,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 18,
issue 9
页码: 1229-1244
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208077220
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The polymerization of isobutylene has been investigated by the use of the steady, slow, continuous monomer addition technique in the presence of a variety of initiating systems, i.e., “H2O”/TiCl4, “H2O”/AlCl3, C6H5C(CH3)2Cl/TiCl4, p-ClCH2C6(CH3)4* CH2Cl/AlCl3at -50°C. Quasiliving polymerizations have been obtained with the “H2O” and C6H5(CH3)2Cl/TiC14systems in 60/40 v/v n-hexane/methylene chloride solvent mixtures with very slow monomer input. After a brief “flash” polymerization, theMnof PIB increased linearly with the cumulative amount of monomer added (consumed); however, the number of polymer molecules formed also increased, indicating the presence of chain transfer to monomer. With the “H2O”/TiCl4initiating system,Mn,maxwas 56,000 andMw/Mn< 2.0. By the use of the C6H5C(CH3)2CL/TiCl4initiating system, quasiliving polymerization has been achieved and chain transfer could virtually be eliminated.
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