Pulsed emission data and ODMR spectra of the 580 nm band provide evidence for an intermediate case exciton in pure and Cd2+-doped AgBr. This interpretation is based on the observed g-factor and the absence of a wavelength shift of the emission after pulsed excitation in pure AgBr. It is supported by the response of the ODMR spectra as the microwave modulation frequency is changed. The two central ODMR lines observed in AgBr (g = 1. 78) are assigned to transitions from the ms=±1 levels to the ms= 0 level of an intermediate case triplet exciton, which has an exchange coupling (singlet-triplet splitting) of -1. 9 ± 0. 2 cm−1.