Dielectric Properties of Single‐Crystal Nonstoichiometric Rutile (TiO2)
作者:
Lewis E. Hollander,
Patricia L. Castro,
期刊:
Journal of Applied Physics
(AIP Available online 1962)
卷期:
Volume 33,
issue 12
页码: 3421-3426
ISSN:0021-8979
年代: 1962
DOI:10.1063/1.1702423
出版商: AIP
数据来源: AIP
摘要:
The dielectric constant &egr;′ and dielectric loss &egr;″ have been determined from 30 to 300 000 cps in theaandccrystal directions for nonstoichiometric compositions of rutile with dc resistivities from 104to 1013&OHgr;‐cm. Measurements with asymmetrical electrodes and geometrical variations indicate that the properties are primarily a bulk effect. Quasi‐ferroelectric effects were observed at field gradients greater than 500 V/cm and at frequencies above 0.5 cps. It is suggested that the dielectric properties of rutile can be explained by an artificial dielectric model consisting of conducting needles of heterogeneously distributed oxygen vacancies embedded in an insulating medium.
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