MIXED-MODE GPC USED TO CONTROL THE REACTION BETWEENN,N-DIMETHYL-PROPYLENE-1,3-DIAMINE AND TRIGLYCERIDES
作者:
J. Poskrobko,
M. Dejnega,
P. Terelak,
W. Jerzykiewicz,
期刊:
Journal of Liquid Chromatography & Related Technologies
(Taylor Available online 1999)
卷期:
Volume 22,
issue 19
页码: 2935-2943
ISSN:1082-6076
年代: 1999
DOI:10.1081/JLC-100102069
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Gel permeation chromatography (GPC) was utilised to control the progress of the reaction betweenN,N-dimethylpropylene-1,3-diamine (DMPDA) and triglycerides (fats). As per “ideal size exclusion mode”, the sample is separated into triglycerides (TGC), diglycerides (DGC), monoglycerides (MGC), and glycerine (GC), as the component groups with sufficiently different molecular weights. Moreover, the separation was obtained for MGC and amidoamines (AA), i.e. the reaction products, despite the fact that their molecular weights are the same in practice (Mw=348 and 358, respectively). The increased retention time for amidoamines was assumed to be accounted for by the additional adsorption effects in “adsorption mode”. Resulting from the overlapping of two types of chromatographic separation mechanisms, an analytical method was obtained which could be called “mixed mode” conditions.
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