In the cane sugar industry the purchase price of raw cane sugar, the product of sugar cane processing, is determined by polarimetric measurement of sucrose content in raw sugar solutions, expressed as Pol. Raw sugar generally contains more than 96% sucrose, but also contains other saccharides and non-sugars which can contribute to Pol. Dextrans, one class of polysaccharides often found in raw sugar, effect an increase in Pol and interfere with subsequent refining. The U.S. sugar refining industry can impose a penalty on the raw sugar purchase price for high dextran content. While there are several wet chemical methods for the determination of dextran in raw sugar, the results of these analyses are rarely in agreement. The existing wet chemical methods for the determination of dextran in raw cane sugar are reviewed and the results of these wet chemical analyses are compared with the results obtained from the physical measurement of dextran in raw sugar by1H NMR spectroscopy.