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Dynamics of the Frederiks transition in nematics consisting of disc-like molecules Thermal dependence of a bend viscosity coefficient

 

作者: T.W. Warmerdam,   R.J. J. Zijlstra,   D. Frenkel,  

 

期刊: Liquid Crystals  (Taylor Available online 1988)
卷期: Volume 3, issue 8  

页码: 1105-1114

 

ISSN:0267-8292

 

年代: 1988

 

DOI:10.1080/02678298808086565

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

We report measurements of the dynamics of the magnetic Frederiks transition in nematics consisting of disc-like molecules. In this paper the results are presented for three 2, 3, 6, 7, 10, 11-hexakis(p-alkoxybenzoyloxy)triphenylenes, which exhibit a normal nematic phase, and for three 2, 3, 7, 8, 12, 13-hexa(alkanoyloxy)truxenes, which exhibit an inverted nematic phase. We find that the thermal dependence of a bend viscosity coefficient (γ*1) can be accurately described by the expression, γ*1∼S2exp (Ea/kT). The absolute value of γ*1is found to be higher (by a factor of 10–100) than is commonly encountered in nematics consisting of rod-like molecules.

 

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