首页   按字顺浏览 期刊浏览 卷期浏览 Rheological properties and domain structures of immiscible polymer blends under steady ...
Rheological properties and domain structures of immiscible polymer blends under steady and oscillatory shear flows

 

作者: Shinichi Kitade,   Akihiro Ichikawa,   Naotomo Imura,   Yoshiaki Takahashi,   Ichiro Noda,  

 

期刊: Journal of Rheology  (AIP Available online 1997)
卷期: Volume 41, issue 5  

页码: 1039-1060

 

ISSN:0148-6055

 

年代: 1997

 

DOI:10.1122/1.550871

 

出版商: The Society of Rheology

 

关键词: Blends;Palierne theory of blends;Doi-Ohta theory

 

数据来源: AIP

 

摘要:

Rheological properties of three immiscible polyisoprene (PI)/polydimethylsiloxane (PDMS) blends (PI:PDMS=1:9by weight) having viscosity ratiosηd/ηm=0.155,0.826, and 4.02, whereηdandηmare the viscosities of the droplet and matrix, were investigated by directly measuring the droplet size distributions with a video microscope. Steady state measurements were performed by sequentially stepping up the shear rateγ̇(step-up) and step decrease (step-down) of the shear rate. Dynamic frequency sweep measurements were also performed immediately following cessation of steady shear flow. In the step-up measurements for blends withηd/ηm=0.155and 0.826, stresses were proportional toγ̇and the droplet sizes were well regulated by the flow and inversely proportional toγ̇forγ̇⩾0.553 s−1,in good agreement with the Doi–Ohta model [J. Chem. Phys.95, 1242–1248 (1991)]. The results of step-down measurements were consistent with dynamic moduli measurements, because the droplet sizes were almost unchanged during these measurements. The results are in accord with Palierne’s model [Rheol. Acta29, 204–214 (1990)]. For theηd/ηm=4.02blend, however, the droplet sizes were insensitive toγ̇,resulting in worse agreement between the experimental and theoretical results than for the other blends.

 

点击下载:  PDF (2814KB)



返 回