Rheological properties and domain structures of immiscible polymer blends under steady and oscillatory shear flows
作者:
Shinichi Kitade,
Akihiro Ichikawa,
Naotomo Imura,
Yoshiaki Takahashi,
Ichiro Noda,
期刊:
Journal of Rheology
(AIP Available online 1997)
卷期:
Volume 41,
issue 5
页码: 1039-1060
ISSN:0148-6055
年代: 1997
DOI:10.1122/1.550871
出版商: The Society of Rheology
关键词: Blends;Palierne theory of blends;Doi-Ohta theory
数据来源: AIP
摘要:
Rheological properties of three immiscible polyisoprene (PI)/polydimethylsiloxane (PDMS) blends (PI:PDMS=1:9by weight) having viscosity ratiosηd/ηm=0.155,0.826, and 4.02, whereηdandηmare the viscosities of the droplet and matrix, were investigated by directly measuring the droplet size distributions with a video microscope. Steady state measurements were performed by sequentially stepping up the shear rateγ̇(step-up) and step decrease (step-down) of the shear rate. Dynamic frequency sweep measurements were also performed immediately following cessation of steady shear flow. In the step-up measurements for blends withηd/ηm=0.155and 0.826, stresses were proportional toγ̇and the droplet sizes were well regulated by the flow and inversely proportional toγ̇forγ̇⩾0.553 s−1,in good agreement with the Doi–Ohta model [J. Chem. Phys.95, 1242–1248 (1991)]. The results of step-down measurements were consistent with dynamic moduli measurements, because the droplet sizes were almost unchanged during these measurements. The results are in accord with Palierne’s model [Rheol. Acta29, 204–214 (1990)]. For theηd/ηm=4.02blend, however, the droplet sizes were insensitive toγ̇,resulting in worse agreement between the experimental and theoretical results than for the other blends.
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