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IR- and UV-Spectral Study of Palladium(II) Complexes with 2-Aminopyridine Obtained in Sulphuric Acid and Alkaline Solutions

 

作者: M. Arnaudov,   Sh. Dinkov,   L. Shishkova,   L. Pindeva,   C. Petrov,   E. Dobreva,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1997）
卷期: Volume 30, issue 8  

页码: 1595-1607

 

ISSN:0038-7010

 

年代: 1997

 

DOI:10.1080/00387019708006746

 

出版商: Taylor & Francis Group

 

关键词: 2-Aminopyridine;Pd (II) complexes;IR- and UV-spectra

 

数据来源: Taylor

 

摘要:

When obtained in sulphuric acid medium sulphato-2-aminopyridine-palladium (II) complex has a polynuclear structure, with a bridging coordination of both the sulphato-group and 2-aminopyridine. The complex keeps its polynuclear structure in alkaline solution, in which the substitution of sulphato ions by hydroxylic groups yields hydroxo-2-aminopyridine-palladium (II). The compounds discussed are the main components of activators used in currentless metallization of nonconducting surfaces.

 

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