The spectrum of ice
作者:
U.P. Johari,
期刊:
Contemporary Physics
(Taylor Available online 1981)
卷期:
Volume 22,
issue 6
页码: 613-642
ISSN:0010-7514
年代: 1981
DOI:10.1080/00107518108231559
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This article reviews experimental and theoretical work on the spectrum of ice. Its features in the radiofrequency region arise from the reorientation of water molecules at lattice sites where strong thermal excitations of a molecular vibration produce a defect. The large permittivity and relaxation time in ice are consistent with our knowledge of its structure. The microwave region has been less extensively studied, but enough information is available to determine how the molecular polarizability of a water molecule in ice depends upon temperature and volume. In the infrared region, two features, arising from the translational lattice vibrations and symmetric O-H stretching, have received much attention, and progress is being made towards understanding them theoretically. The visible and ultraviolet regions show no distinctive features, and the absorptivity in this region is small.
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