The spectrum of ice

 

作者: U.P. Johari,  

 

期刊: Contemporary Physics  (Taylor Available online 1981)
卷期: Volume 22, issue 6  

页码: 613-642

 

ISSN:0010-7514

 

年代: 1981

 

DOI:10.1080/00107518108231559

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

This article reviews experimental and theoretical work on the spectrum of ice. Its features in the radiofrequency region arise from the reorientation of water molecules at lattice sites where strong thermal excitations of a molecular vibration produce a defect. The large permittivity and relaxation time in ice are consistent with our knowledge of its structure. The microwave region has been less extensively studied, but enough information is available to determine how the molecular polarizability of a water molecule in ice depends upon temperature and volume. In the infrared region, two features, arising from the translational lattice vibrations and symmetric O-H stretching, have received much attention, and progress is being made towards understanding them theoretically. The visible and ultraviolet regions show no distinctive features, and the absorptivity in this region is small.

 

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