Radical-Initiated Homopolymerization of Acrylonitrile in the Presence of Ce(Iv)-Hippuric Acid in Iviicellar Phase: A Kinetic Study
作者:
B.D. Behera,
E. Mohanty,
C.M. Patra,
B.C. Singh,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1995)
卷期:
Volume 34,
issue 1
页码: 1-16
ISSN:0360-2559
年代: 1995
DOI:10.1080/03602559508017209
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Polymerization of acrylonitrile using Ce(IV) as initiator in the presence of hippuric acid in aqueous sulfuric acid solution catalyzed byN-cetyl trimethyl ammonium bromide (NCTAB) was studied kinetically. The polymerization experiment was carried out in the temperature range 35°-55°C. The rate of polymerization (Rp) increases with increasing concentration of NCTAB and it is found to be proportional to the concentration of acrylonitrile. Comparisons were made of the effect of different organic substrates and different miceiles on the rate of polymerization. Various effects such as effects of concentration of metal ion, ernulsi-fier, monomer, sulfuric acid, organic solvents, and inorganic salts onRpwere also investigated. The remarkable feature of the investigation involves the enhancement ofRpin the presence of micelles; a suitable mechanism for the derivation of the rate expression is proposed and optimum conditions are predicted. From the Arrhenius plot, the energy of activation (EA) was found to be 1.9805 kcal/mol.
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