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Polyisocyanides, synthesis and isomerization to polycyanides

 

作者: R. J. M. Nolte,   R. W. Stephany,   W. Drenth,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1973）
卷期: Volume 92, issue 1  

页码: 83-91

 

ISSN:0165-0513

 

年代: 1973

 

DOI:10.1002/recl.19730920109

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractNi(C2H5OH) (t‐C4H9NC)Cl2and nickel acetylacetonate are effective catalysts for the polymerization of isocyanides. Protic solvents and the presence of an acid accelerate the polymerization in case of nickel acetylacetonate. The reaction products are characterized as poly‐Schiff bases. Upon treatment with acid the polymers of primary alkyl isocyanides rearrange to polycyani

 

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