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Conoscopic and X-ray diffraction study of the molecular and lamellar orientation in LDPE films

 

作者: E. Nedkov,   L. Minkova,   M. Nikolova,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1987)
卷期: Volume 26, issue 4  

页码: 465-478

 

ISSN:0022-2348

 

年代: 1987

 

DOI:10.1080/00222348708223948

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

By means of conoscopic and WAXS methods, the type of lamellar orientation in a LDPE blown film has been investigated. The WAXS diffractograms establish the existence of plane-axial texture, the crystallographic a axis of the unit cell being predominantly parallel to the machine-processing direction (the M axis) of the film. The conoscopic data indicate that the film as a whole behaves like an optically positive biaxial monocrystal, the plane of the film being a section perpendicular to the obtuse bisectrix. Comparison of the experimental data of both methods leads to the conclusion that the b and c axes of the unit cell may occupy any arbitrary position in a plane perpendicular to M.

 

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