Effect of Pressure on Ultrasonic Absorption, Multistate Dissociation, and Chemical Equilibrium inMnSO4Solutions
作者:
F. H. Fisher,
W. M. Wright,
期刊:
The Journal of the Acoustical Society of America
(AIP Available online 1969)
卷期:
Volume 46,
issue 3B
页码: 574-579
ISSN:0001-4966
年代: 1969
DOI:10.1121/1.1911733
出版商: Acoustical Society of America
数据来源: AIP
摘要:
Measurements were made on the effect of pressure on ultrasonic absorption in a 0.5Maqueous solution of manganese sulfate at 25°C. A cylindrical resonant cavity was used for obtaining absorption in the frequency regions of 300 and 500 kHz, at pressures up to 20 000 psi. Results are similar to those obtained forMgSO4, in that absorption decreases by a factor of about 3 for a pressure increase of 15 000 psi. Independent conductivity data show nearly the same behavior forMnSO4as forMgSO4solutions, namely, an increase of only about 14% in the concentration of dissociated ions for the same pressure increase. These results forMnSO4appear to be inconsistent with the model used by Atkinson and Kor to analyze their data. The large effect of pressure on ultrasonic absorption is similar to that observed by Carnevale for 0.1MMnSO4at 60°C from 9 to 75 MHz.
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